
The Department of Macromolecular Physics was established as the Department of Polymers in 1974. At present, our department is conducting research in the fields of physics of nanomaterials, physics of polymers and macromolecular solids and theoretical physics.
News

Members of our department participated in a study focused on the development and characterization of electrodes with increased photoactivity based on a combination of TiO2 nanotubes and MXenes. The results of this study, which are particularly interesting with regard to possible applications of these materials in photoelectrochemical and optoelectrochemical systems, are summarized in the article "Laser-Treated MXene as an Electrochemical Agent to Boost Properties of Semitransparent Photoelectrode Based on Titania Nanotubes" just published in the journal ACSNano.

In a paper published in the journal Advanced Optical Materials, a group led by A. Shukurov demonstrated that stoichiometric and crystalline HfN nanoparticles with tunable optical response can be produced in the gas phase using reactive magnetron sputtering – a technique with a small ecological footprint. In addition, it has been proven that the nanoparticles are highly stable even during UHV annealing up to 800 °C, which is attractive for their use, for example, in space missions.

In an article published in the journal Nanoscale, the group of A. Shukurov described the first successful synthesis of cubic, crystalline, stoichiometric, electrically conductive and plasmonic ZrN nanoparticles in the gas phase using reactive magnetron sputtering without the use of aggressive chemicals or high temperatures. ZrN nanoparticles were deposited directly even into vacuum-compatible liquids. The nanofluids prepared in this way have a beautiful turquoise color, given by localized surface plasmon resonance, and do not contain any chemical residues or additives.

As part of an international project with partners from Poland and the University of South Bohemia in České Budějovice, we participated in the development of a unique type of semitransparent double-sided photoelectrode based on TiO2 nanotubes. In a study just published in the journal Renewable & Sustainable Energy Reviews, we have demonstrated the possibility of using plasma methods and subsequent anodization to prepare TiO2 nanotubes with different morphologies on both sides of the photoelectrode, which paves the way for the development of advanced photoelectrochemical and light-harvesting systems.

Is it possible to use plasma in agriculture? The article "Plasma Treatment Modifies Element Distribution in Seed Coating and Affects Further Germination and Plant Growth through Interaction with Soil Microbiome", which was just published in the Journal of Agricultural and Food Chemistry, and in which O. Kylián participated, tries to find an answer to this question.

We would like to congratulate V. Holubec on being one of only two scientists from the Czech Republic to be awarded APS’s 2024 Outstanding Referee.
More details and a complete list of awarded scientists may be found here.

Together with colleagues from the Institute of Physics of the Academy of Sciences of the Czech Republic, we are organizing a traditional German-Czech workshop on nanomaterials. This workshop will be held on June 10 and 11, 2024 in the premises of the Institute of Physics.
More details may be found here.

Congratulations to our students for receiving funding for their research projects from the Charles University Grant Agency! Greetings come to:
- D. Voráč: Elusive delayed interactions in active matter
models - E.P. Cital: Generalization of thermodynamic uncertainty relations for underdamped systems

Z. Krtouš and V. Březina received funds to cover the costs associated with their internships at prestigious foreign institutions:
- V. Březina: Peter-Debye-Institute fro Soft Matter Physics, Uni Leipzig, Germany
- Z. Krtouš: University of California, Santa Barbara, USA

Nanoparticles of metal oxides have very wide applications in various fields. As we have shown in the just published article in Ceramics International, an interesting application of V2O5 nanoparticles is their use as a platform for non-plasmonic surface-enhanced Raman spectroscopy.

As part of an international scientific project, we participated in the development and preparation of new semi-transparent titanium oxide nanotubular coatings doped with silver with tunable morphology.
The results of this study were published in the journal ACS Applied Nano Materials.

As the recent epidemic of COVID-19 has shown, to ensure safety, it is necessary to have materials available that enable the effective destruction of viruses. O. Kylián, in cooperation with JU, participated in the development of a unique antiviral coating for respirators, which is based on galvanic corrosion of copper. More can be found in the publication published in the journal ACS Applied Nano Materials.

Since the 1st of January 2024, two new GAČR projects will be running in our department:
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Plasma-assisted synthesis of hybrid nanomaterials for laser-driven proton-boron nuclear fusion (A. Shukurov)
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Nanomaterials based on conductive polymers for surface-enhanced Raman spectroscopy
(O.Kylián)

Metallic nanofluids consisting of Ag nanoparticles prepared using a gas aggregation source and poly(ethylene glycol) demonstrated a memristive (memory) effect. Nanoparticles form 3D conductive bridges in an electric field. The electric current passing through the bridges has a jumping character, reminiscent of the process of information transmission in biological neural networks. These results were published in Advanced Functional Materials.

At the conference XII iPlasmaNano, which was organised on the French island Guadeloupe, O.Kylián gave an invited lecture "Magnetron-based gas aggregation sources of nanoparticles: state-of-the-art, challenges and future perspectives".

At the 13th Asian-European International Conference on Plasma Surface Engineering in Busan, Korea, Professor Andrey Shukurov gave an invited lecture on 'One-Step Sputter-Driven Synthesis of Metal Nitride Nanoparticles and Nanofluids'.
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